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University Quantum Mechanics I · topic UQMI-14.04

Spherical coordinates, the Laplacian, and the volume element

Connect the ideas, make your working visible, and test the result. Use the hints when you need a starting point; open the full solution after your attempt.

Further practice

Work through a fresh case before tackling the extension.

Further practice · 01

Spherical coordinates, the Laplacian, and the volume element: predict a finite change

Spherical coordinates label a point by its distance r from the origin, its polar angle θ from the +z axis and its azimuth φ around that axis; in them a small volume is dV = r² sin θ dr dθ dφ, not dr dθ dφ. Use the supplied topic model Y_out = r*sind(theta), where Y_out is DISTANCE FROM z AXIS r sin θ (nm). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793; sind/cosd/tand use degrees. theta is Polar angle θ, measured in °. Keep r (Radius r) = 1.2 nm fixed. For this exercise use only 17.5313 ° ≤ theta ≤ 86.8312 ° on this continuous branch. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. Calculate Y_out at theta = 32.7772 ° and 42.4792 °. Find the signed output change ΔY_out and the average sensitivity ΔY_out/Δtheta across this interval. State whether the response increases or decreases; distinguish this interval average from a derivative at one point.

Explore the question data

DISTANCE FROM z AXIS r sin θ against theta

Predictions from the supplied Spherical coordinates, the Laplacian, and the volume element model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law.

Vertical axis (y): DISTANCE FROM z AXIS r sin θ / nm

DISTANCE FROM z AXIS r sin θ against thetaPredictions from the supplied Spherical coordinates, the Laplacian, and the volume element model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law. Horizontal axis: theta: Polar angle θ / °. Vertical axis: DISTANCE FROM z AXIS r sin θ / nm. Exact values are available in the data table below.0.3280.55390.77981.0061.23214.7633.4752.1870.8989.6xy

Horizontal axis (x): theta: Polar angle θ / °

Axes show the supplied calibration interval; the origin may lie outside the plot.

Reading 1theta: Polar angle θ / °: 17.53DISTANCE FROM z AXIS r sin θ / nm: 0.3615
Read the exact data as a table
DISTANCE FROM z AXIS r sin θ against theta — supplied values
theta: Polar angle θ / °DISTANCE FROM z AXIS r sin θ / nm
17.531250.36147111198677334
34.856250.6858233446450177
52.181250.9479452760463911
69.506251.1240524624496506
86.831251.198165273897687

These are the supplied values, not a worked answer. No fitted trend is drawn.

Show a hint

Substitute each value of theta separately while keeping every other input fixed, then subtract in the same order.

Reveal the worked solution
  1. At theta = 32.7772 °, substitute into Y_out = r*sind(theta): Y₀ = 0.649649 nm.
  2. At theta = 42.4792 °, the same fixed-parameter model gives Y₁ = 0.810388 nm.
  3. Signed change: ΔY_out = Y₁ − Y₀ = 0.160738 nm; the input change is Δtheta = 9.702 °.
  4. Average sensitivity is ΔY_out/Δtheta = 0.0165676 nm per °. Its positive sign means that this response increases over the specified interval.
  5. This is a secant slope between two settings. It equals a point derivative only for a locally linear relation or in a justified small-interval limit.

Answer Y₀ = 0.649649 nm, Y₁ = 0.810388 nm; ΔY_out = 0.160738 nm; average sensitivity = 0.0165676 nm per °.

Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.

Extra challenging questions

Work through the linked stages and explain what each result means.

Extra challenging · 01

Spherical coordinates, the Laplacian, and the volume element: infer an input with uncertainty

Spherical coordinates label a point by its distance r from the origin, its polar angle θ from the +z axis and its azimuth φ around that axis; in them a small volume is dV = r² sin θ dr dθ dφ, not dr dθ dφ. Use the supplied topic model Y_out = r*sind(theta), where Y_out is DISTANCE FROM z AXIS r sin θ (nm). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793; sind/cosd/tand use degrees. theta is Polar angle θ, measured in °. Keep r (Radius r) = 1.2 nm fixed. For this exercise use only 17.5313 ° ≤ theta ≤ 86.8312 ° on this continuous branch. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. A reading gives Y_out = 1.0371745 nm, with a bounded reading uncertainty ±0.024149 nm. Treat the model and all fixed inputs as exact for this exercise; the bound is not a standard deviation. First estimate the unknown theta by straight-line interpolation between the two endpoint predictions. Then solve the actual model on the stated branch to an absolute input tolerance of 0.00693 °, using a numerical bracket if required. Find the full input interval consistent with the bounded reading uncertainty and compare it with a symmetric input-error assumption. Do not assume that the supplied calibration points prove monotonicity outside this branch.

Explore the question data

DISTANCE FROM z AXIS r sin θ against theta

Predictions from the supplied Spherical coordinates, the Laplacian, and the volume element model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law.

Vertical axis (y): DISTANCE FROM z AXIS r sin θ / nm

DISTANCE FROM z AXIS r sin θ against thetaPredictions from the supplied Spherical coordinates, the Laplacian, and the volume element model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law. Horizontal axis: theta: Polar angle θ / °. Vertical axis: DISTANCE FROM z AXIS r sin θ / nm. Exact values are available in the data table below.0.3280.55390.77981.0061.23214.7633.4752.1870.8989.6xy

Horizontal axis (x): theta: Polar angle θ / °

Axes show the supplied calibration interval; the origin may lie outside the plot.

Reading 1theta: Polar angle θ / °: 17.53DISTANCE FROM z AXIS r sin θ / nm: 0.3615
Read the exact data as a table
DISTANCE FROM z AXIS r sin θ against theta — supplied values
theta: Polar angle θ / °DISTANCE FROM z AXIS r sin θ / nm
17.531250.36147111198677334
34.856250.6858233446450177
52.181250.9479452760463911
69.506251.1240524624496506
86.831251.198165273897687

These are the supplied values, not a worked answer. No fitted trend is drawn.

Show a hint

The model's endpoint predictions bracket the reading. Solve Y_out(theta) = Y_measured and then solve again at Y_measured − u and Y_measured + u; a nonlinear inverse can give unequal input deviations.

Reveal the worked solution
  1. Endpoint predictions are Y_out(17.5313) = 0.361471 nm and Y_out(86.8312) = 1.19817 nm. The target lies between them. On the selected branch the response is strictly increasing.
  2. Endpoint interpolation gives theta_line = 17.5313 + (1.03717 − 0.361471)(86.8312 − 17.5313)/(1.19817 − 0.361471) = 73.497 °. This estimates the inverse of the endpoint chord, rather than assuming that chord is the physical model.
  3. Use the actual equation, not the chord, and bracket its root. Evaluating the midpoint and retaining the sign-changing half-interval gives theta = 59.8042 °; substituting back gives Y_out = 1.0371745 nm.
  4. The interpolation error in the input is |theta_line − theta| = 13.6928 °. This is larger than the requested numerical tolerance.
  5. Invert both limits Y_out = 1.0130255 nm and 1.0613235 nm. Sort the roots even if the response decreases: 57.585 ° ≤ theta ≤ 62.1822 °.
  6. The lower and upper input deviations are 2.21921 ° and 2.37798 °. They differ because the inverse response is nonlinear; a symmetric error bar would only be a local approximation. This interval includes reading uncertainty only, not model error or uncertainty in fixed inputs.

Answer theta ≈ 59.8042 °; compatible interval [57.585, 62.1822] °. Endpoint interpolation gives 73.497 °.

Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.