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University Quantum Mechanics II · unit UQMII-11

Semiclassical Methods: WKB and the Path Integral

Connect the ideas, make your working visible, and test the result. Use the hints when you need a starting point; open the full solution after your attempt.

Extra challenging questions

A selection from this pathway. Open a topic below for its complete practice and challenge set.

Extra challenging · 01

The propagator, and the free particle's in closed form: infer an input with uncertainty

The propagator K(x, t; x′, 0) = ⟨x|e^(−iHt/ħ)|x′⟩ is the amplitude for a particle released exactly at x′ to be found at x a time t later; integrating it against any initial wavefunction gives the wavefunction at t. Use the supplied topic model Y_out = 1.374779/t, where Y_out is |K₀|² AT EVERY x (nm⁻²). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793. t is Time since release t, measured in fs. Keep d (Marked point x = d) = 2 nm; s (Width of a launched packet σ₀) = 0.5 nm fixed. For this exercise use only 1.95625 fs ≤ t ≤ 9.04375 fs on this continuous branch. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. A reading gives Y_out = 0.21892693 nm⁻², with a bounded reading uncertainty ±0.010037 nm⁻². Treat the model and all fixed inputs as exact for this exercise; the bound is not a standard deviation. First estimate the unknown t by straight-line interpolation between the two endpoint predictions. Then solve the actual model on the stated branch to an absolute input tolerance of 0.00070875 fs, using a numerical bracket if required. Find the full input interval consistent with the bounded reading uncertainty and compare it with a symmetric input-error assumption. Do not assume that the supplied calibration points prove monotonicity outside this branch.

Explore the question data

|K₀|² AT EVERY x against t

Predictions from the supplied The propagator, and the free particle's in closed form model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law.

Vertical axis (y): |K₀|² AT EVERY x / nm⁻²

|K₀|² AT EVERY x against tPredictions from the supplied The propagator, and the free particle's in closed form model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law. Horizontal axis: t: Time since release t / fs. Vertical axis: |K₀|² AT EVERY x / nm⁻². Exact values are available in the data table below.0.130.27870.42740.57610.72481.6733.5865.57.4149.327xy

Horizontal axis (x): t: Time since release t / fs

Axes show the supplied calibration interval; the origin may lie outside the plot.

Reading 1t: Time since release t / fs: 1.956|K₀|² AT EVERY x / nm⁻²: 0.7028
Read the exact data as a table
|K₀|² AT EVERY x against t — supplied values
t: Time since release t / fs|K₀|² AT EVERY x / nm⁻²
1.95624999999999980.702762428115016
3.72812499999999950.3687588264878458
5.50.24995981818181817
7.2718750.18905426729694888
9.043750.15201426399447132

These are the supplied values, not a worked answer. No fitted trend is drawn.

Show a hint

The model's endpoint predictions bracket the reading. Solve Y_out(t) = Y_measured and then solve again at Y_measured − u and Y_measured + u; a nonlinear inverse can give unequal input deviations.

Reveal the worked solution
  1. Endpoint predictions are Y_out(1.95625) = 0.702762 nm⁻² and Y_out(9.04375) = 0.152014 nm⁻². The target lies between them. On the selected branch the response is strictly decreasing.
  2. Endpoint interpolation gives t_line = 1.95625 + (0.218927 − 0.702762)(9.04375 − 1.95625)/(0.152014 − 0.702762) = 8.18266 fs. This estimates the inverse of the endpoint chord, rather than assuming that chord is the physical model.
  3. Use the actual equation, not the chord, and bracket its root. Evaluating the midpoint and retaining the sign-changing half-interval gives t = 6.27962 fs; substituting back gives Y_out = 0.21892693 nm⁻².
  4. The interpolation error in the input is |t_line − t| = 1.90304 fs. This is larger than the requested numerical tolerance.
  5. Invert both limits Y_out = 0.20888993 nm⁻² and 0.22896393 nm⁻². Sort the roots even if the response decreases: 6.00435 fs ≤ t ≤ 6.58136 fs.
  6. The lower and upper input deviations are 0.275277 fs and 0.301731 fs. They differ because the inverse response is nonlinear; a symmetric error bar would only be a local approximation. This interval includes reading uncertainty only, not model error or uncertainty in fixed inputs.

Answer t ≈ 6.27962 fs; compatible interval [6.00435, 6.58136] fs. Endpoint interpolation gives 8.18266 fs.

Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.

Extra challenging · 02

Time slicing and Feynman's path integral: infer an input with uncertainty

Feynman's path integral is the propagator written as the N → ∞ limit of (m/(2πiħε))^(N/2) times an integral over the N − 1 intermediate positions of a path cut into slices of time ε = t/N, each path weighted by exp(iS_N/ħ). Use the supplied topic model Y_out = c^2*(2*n-3), where Y_out is ZIGZAG EXTRA PHASE (rad). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793. c is Zigzag tooth c, in Fresnel lengths, measured in √(ħε/m). Keep n (Number of slices N) = 6 fixed. For this exercise use only 0.2125 √(ħε/m) ≤ c ≤ 1.7875 √(ħε/m) on this continuous branch. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. A reading gives Y_out = 12.38864 rad, with a bounded reading uncertainty ±1.7973 rad. Treat the model and all fixed inputs as exact for this exercise; the bound is not a standard deviation. First estimate the unknown c by straight-line interpolation between the two endpoint predictions. Then solve the actual model on the stated branch to an absolute input tolerance of 0.0001575 √(ħε/m), using a numerical bracket if required. Find the full input interval consistent with the bounded reading uncertainty and compare it with a symmetric input-error assumption. Do not assume that the supplied calibration points prove monotonicity outside this branch.

Explore the question data

ZIGZAG EXTRA PHASE against c

Predictions from the supplied Time slicing and Feynman's path integral model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law.

Vertical axis (y): ZIGZAG EXTRA PHASE / rad

ZIGZAG EXTRA PHASE against cPredictions from the supplied Time slicing and Feynman's path integral model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law. Horizontal axis: c: Zigzag tooth c, in Fresnel lengths / √(ħε/m). Vertical axis: ZIGZAG EXTRA PHASE / rad. Exact values are available in the data table below.-0.72766.92714.5822.2429.890.14950.574711.4251.85xy

Horizontal axis (x): c: Zigzag tooth c, in Fresnel lengths / √(ħε/m)

Axes show the supplied calibration interval; the origin may lie outside the plot.

Reading 1c: Zigzag tooth c, in Fresnel lengths / √(ħε/m): 0.2125ZIGZAG EXTRA PHASE / rad: 0.4064
Read the exact data as a table
ZIGZAG EXTRA PHASE against c — supplied values
c: Zigzag tooth c, in Fresnel lengths / √(ħε/m)ZIGZAG EXTRA PHASE / rad
0.21250.40640624999999997
0.606253.3078515625
19
1.393749999999999817.482851562499995
1.787499999999999928.756406249999998

These are the supplied values, not a worked answer. No fitted trend is drawn.

Show a hint

The model's endpoint predictions bracket the reading. Solve Y_out(c) = Y_measured and then solve again at Y_measured − u and Y_measured + u; a nonlinear inverse can give unequal input deviations.

Reveal the worked solution
  1. Endpoint predictions are Y_out(0.2125) = 0.406406 rad and Y_out(1.7875) = 28.7564 rad. The target lies between them. On the selected branch the response is strictly increasing.
  2. Endpoint interpolation gives c_line = 0.2125 + (12.3886 − 0.406406)(1.7875 − 0.2125)/(28.7564 − 0.406406) = 0.87818 √(ħε/m). This estimates the inverse of the endpoint chord, rather than assuming that chord is the physical model.
  3. Use the actual equation, not the chord, and bracket its root. Evaluating the midpoint and retaining the sign-changing half-interval gives c = 1.17325 √(ħε/m); substituting back gives Y_out = 12.38864 rad.
  4. The interpolation error in the input is |c_line − c| = 0.29507 √(ħε/m). This is larger than the requested numerical tolerance.
  5. Invert both limits Y_out = 10.59134 rad and 14.18594 rad. Sort the roots even if the response decreases: 1.08481 √(ħε/m) ≤ c ≤ 1.25547 √(ħε/m).
  6. The lower and upper input deviations are 0.0884387 √(ħε/m) and 0.0822242 √(ħε/m). They differ because the inverse response is nonlinear; a symmetric error bar would only be a local approximation. This interval includes reading uncertainty only, not model error or uncertainty in fixed inputs.

Answer c ≈ 1.17325 √(ħε/m); compatible interval [1.08481, 1.25547] √(ħε/m). Endpoint interpolation gives 0.87818 √(ħε/m).

Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.

Extra challenging · 03

Stationary phase and the classical limit: infer an input with uncertainty

Stationary phase approximates an integral of e^(iφ/ħ) with φ ≫ ħ by keeping only the neighbourhood of the points where φ is stationary; applied to the path integral, it keeps the classical path and the Gaussian fluctuations around it. Use the supplied topic model Y_out = sqrt(pi*wt/180/max(abs(sind(wt)),0.001)), where Y_out is PREFACTOR |K_osc|/|K_free| (dimensionless). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793; sqrt(x) means √x; abs(x) means |x|; max(a,b) selects the larger value; sind/cosd/tand use degrees. wt is End time ωt, measured in °. Keep act (Action scale mωL²/ħ) = 10 fixed. For this exercise use only 82.05 ° ≤ wt ≤ 172.14 ° on this continuous branch. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. A reading gives Y_out = 1.8725567, with a bounded reading uncertainty ±0.10051. Treat the model and all fixed inputs as exact for this exercise; the bound is not a standard deviation. First estimate the unknown wt by straight-line interpolation between the two endpoint predictions. Then solve the actual model on the stated branch to an absolute input tolerance of 0.009009 °, using a numerical bracket if required. Find the full input interval consistent with the bounded reading uncertainty and compare it with a symmetric input-error assumption. Do not assume that the supplied calibration points prove monotonicity outside this branch.

Explore the question data

PREFACTOR |K_osc|/|K_free| against wt

Predictions from the supplied Stationary phase and the classical limit model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law.

Vertical axis (y): PREFACTOR |K_osc|/|K_free|

PREFACTOR |K_osc|/|K_free| against wtPredictions from the supplied Stationary phase and the classical limit model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law. Horizontal axis: wt: End time ωt / °. Vertical axis: PREFACTOR |K_osc|/|K_free|. Exact values are available in the data table below.1.0632.0042.9453.8864.82778.45102.8127.1151.4175.7xy

Horizontal axis (x): wt: End time ωt / °

Axes show the supplied calibration interval; the origin may lie outside the plot.

Reading 1wt: End time ωt / °: 82.05PREFACTOR |K_osc|/|K_free|: 1.202
Read the exact data as a table
PREFACTOR |K_osc|/|K_free| against wt — supplied values
wt: End time ωt / °PREFACTOR |K_osc|/|K_free|
82.051.202472189951345
104.572499999999991.3732445352493772
127.0951.6676326486432869
149.61752.272234862499181
172.144.687174707745816

These are the supplied values, not a worked answer. No fitted trend is drawn.

Show a hint

The model's endpoint predictions bracket the reading. Solve Y_out(wt) = Y_measured and then solve again at Y_measured − u and Y_measured + u; a nonlinear inverse can give unequal input deviations.

Reveal the worked solution
  1. Endpoint predictions are Y_out(82.05) = 1.20247 and Y_out(172.14) = 4.68717. The target lies between them. On the selected branch the response is strictly increasing.
  2. Endpoint interpolation gives wt_line = 82.05 + (1.87256 − 1.20247)(172.14 − 82.05)/(4.68717 − 1.20247) = 99.3737 °. This estimates the inverse of the endpoint chord, rather than assuming that chord is the physical model.
  3. Use the actual equation, not the chord, and bracket its root. Evaluating the midpoint and retaining the sign-changing half-interval gives wt = 137.005 °; substituting back gives Y_out = 1.8725567.
  4. The interpolation error in the input is |wt_line − wt| = 37.6312 °. This is larger than the requested numerical tolerance.
  5. Invert both limits Y_out = 1.7720467 and 1.9730667. Sort the roots even if the response decreases: 132.548 ° ≤ wt ≤ 140.844 °.
  6. The lower and upper input deviations are 4.45719 ° and 3.83876 °. They differ because the inverse response is nonlinear; a symmetric error bar would only be a local approximation. This interval includes reading uncertainty only, not model error or uncertainty in fixed inputs.

Answer wt ≈ 137.005 °; compatible interval [132.548, 140.844] °. Endpoint interpolation gives 99.3737 °.

Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.

Extra challenging · 04

The WKB wavefunction from an ħ expansion, and its validity: infer an input with uncertainty

The WKB wavefunction is the solution of the Schrödinger equation correct through first order in ħ, ψ ≈ (C/√p) exp(±(i/ħ)∫p dx), trustworthy wherever the reduced wavelength ħ/p changes by a small fraction of itself over a distance ħ/p. Use the supplied topic model Y_out = up/((2*n+1)*(1-up^2)^1.5), where Y_out is δ AT THE PROBE (dimensionless). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793. up is Probe position u = x/x_t, dimensionless. Keep n (Quantum number n) = 10 fixed. For this exercise use only 0.104125 ≤ up ≤ 0.875875 on this continuous branch. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. A reading gives Y_out = 0.049973852, with a bounded reading uncertainty ±0.0067401. Treat the model and all fixed inputs as exact for this exercise; the bound is not a standard deviation. First estimate the unknown up by straight-line interpolation between the two endpoint predictions. Then solve the actual model on the stated branch to an absolute input tolerance of 0.000077175, using a numerical bracket if required. Find the full input interval consistent with the bounded reading uncertainty and compare it with a symmetric input-error assumption. Do not assume that the supplied calibration points prove monotonicity outside this branch.

Explore the question data

δ AT THE PROBE against up

Predictions from the supplied The WKB wavefunction from an ħ expansion, and its validity model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law.

Vertical axis (y): δ AT THE PROBE

δ AT THE PROBE against upPredictions from the supplied The WKB wavefunction from an ħ expansion, and its validity model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law. Horizontal axis: up: Probe position u = x/x_t. Vertical axis: δ AT THE PROBE. Exact values are available in the data table below.-0.0096070.089260.18810.2870.38590.073260.28160.490.69840.9067xy

Horizontal axis (x): up: Probe position u = x/x_t

Axes show the supplied calibration interval; the origin may lie outside the plot.

Reading 1up: Probe position u = x/x_t: 0.1041δ AT THE PROBE: 0.00504
Read the exact data as a table
δ AT THE PROBE against up — supplied values
up: Probe position u = x/x_tδ AT THE PROBE
0.1041250.005040077659728858
0.29706250.01624845653703022
0.490.035224279499582435
0.68293750.08343386544295467
0.8758750.3712172081652925

These are the supplied values, not a worked answer. No fitted trend is drawn.

Show a hint

The model's endpoint predictions bracket the reading. Solve Y_out(up) = Y_measured and then solve again at Y_measured − u and Y_measured + u; a nonlinear inverse can give unequal input deviations.

Reveal the worked solution
  1. Endpoint predictions are Y_out(0.104125) = 0.00504008 and Y_out(0.875875) = 0.371217. The target lies between them. On the selected branch the response is strictly increasing.
  2. Endpoint interpolation gives up_line = 0.104125 + (0.0499739 − 0.00504008)(0.875875 − 0.104125)/(0.371217 − 0.00504008) = 0.198827. This estimates the inverse of the endpoint chord, rather than assuming that chord is the physical model.
  3. Use the actual equation, not the chord, and bracket its root. Evaluating the midpoint and retaining the sign-changing half-interval gives up = 0.574893; substituting back gives Y_out = 0.049973852.
  4. The interpolation error in the input is |up_line − up| = 0.376066. This is larger than the requested numerical tolerance.
  5. Invert both limits Y_out = 0.043233752 and 0.056713952. Sort the roots even if the response decreases: 0.540593 ≤ up ≤ 0.603602.
  6. The lower and upper input deviations are 0.0342994 and 0.0287098. They differ because the inverse response is nonlinear; a symmetric error bar would only be a local approximation. This interval includes reading uncertainty only, not model error or uncertainty in fixed inputs.

Answer up ≈ 0.574893; compatible interval [0.540593, 0.603602]. Endpoint interpolation gives 0.198827.

Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.

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