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University Quantum Mechanics II · course UQMII

University Quantum Mechanics II

Connect the ideas, make your working visible, and test the result. Use the hints when you need a starting point; open the full solution after your attempt.

Extra challenging questions

A selection from this pathway. Open a topic below for its complete practice and challenge set.

Extra challenging · 01

The associated Legendre equation and its poles: infer an input with uncertainty

The associated Legendre equation is the polar part of the angular equation written in x = cos θ; its only singular points on the sphere are the poles x = ±1, and at each pole exactly one of its two solutions is regular. Use the supplied topic model Y_out = 57.29578*10^(-n), where Y_out is CAP HALF-ANGLE θ₀ (°). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793. n is Cap size n, with θ₀ = 10^(−n) rad, dimensionless. Keep m (|m|, azimuthal quantum number) = 0 fixed. For this exercise use only 0.978125 ≤ n ≤ 4.52187 on this continuous branch. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. A reading gives Y_out = 0.041525047 °, with a bounded reading uncertainty ±0.0059703 °. Treat the model and all fixed inputs as exact for this exercise; the bound is not a standard deviation. First estimate the unknown n by straight-line interpolation between the two endpoint predictions. Then solve the actual model on the stated branch to an absolute input tolerance of 0.000354375, using a numerical bracket if required. Find the full input interval consistent with the bounded reading uncertainty and compare it with a symmetric input-error assumption. Do not assume that the supplied calibration points prove monotonicity outside this branch.

Explore the question data

CAP HALF-ANGLE θ₀ against n

Predictions from the supplied The associated Legendre equation and its poles model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law.

Vertical axis (y): CAP HALF-ANGLE θ₀ / °

CAP HALF-ANGLE θ₀ against nPredictions from the supplied The associated Legendre equation and its poles model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law. Horizontal axis: n: Cap size n, with θ₀ = 10^(−n) rad. Vertical axis: CAP HALF-ANGLE θ₀ / °. Exact values are available in the data table below.-0.23921.3873.0144.646.2670.83641.7932.753.7074.664xy

Horizontal axis (x): n: Cap size n, with θ₀ = 10^(−n) rad

Axes show the supplied calibration interval; the origin may lie outside the plot.

Reading 1n: Cap size n, with θ₀ = 10^(−n) rad: 0.9781CAP HALF-ANGLE θ₀ / °: 6.026
Read the exact data as a table
CAP HALF-ANGLE θ₀ against n — supplied values
n: Cap size n, with θ₀ = 10^(−n) radCAP HALF-ANGLE θ₀ / °
0.97812499999999996.025563063026317
1.86406249999999970.7835381305946377
2.750.10188790585611991
3.63593750.013249062112480949
4.5218750.0017228506699142692

These are the supplied values, not a worked answer. No fitted trend is drawn.

Show a hint

The model's endpoint predictions bracket the reading. Solve Y_out(n) = Y_measured and then solve again at Y_measured − u and Y_measured + u; a nonlinear inverse can give unequal input deviations.

Reveal the worked solution
  1. Endpoint predictions are Y_out(0.978125) = 6.02556 ° and Y_out(4.52187) = 0.00172285 °. The target lies between them. On the selected branch the response is strictly decreasing.
  2. Endpoint interpolation gives n_line = 0.978125 + (0.041525 − 6.02556)(4.52187 − 0.978125)/(0.00172285 − 6.02556) = 4.49846. This estimates the inverse of the endpoint chord, rather than assuming that chord is the physical model.
  3. Use the actual equation, not the chord, and bracket its root. Evaluating the midpoint and retaining the sign-changing half-interval gives n = 3.13981; substituting back gives Y_out = 0.041525047 °.
  4. The interpolation error in the input is |n_line − n| = 1.35865. This is larger than the requested numerical tolerance.
  5. Invert both limits Y_out = 0.035554747 ° and 0.047495347 °. Sort the roots even if the response decreases: 3.08147 ≤ n ≤ 3.20723.
  6. The lower and upper input deviations are 0.0583409 and 0.0674125. They differ because the inverse response is nonlinear; a symmetric error bar would only be a local approximation. This interval includes reading uncertainty only, not model error or uncertainty in fixed inputs.

Answer n ≈ 3.13981; compatible interval [3.08147, 3.20723]. Endpoint interpolation gives 4.49846.

Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.

Extra challenging · 02

Centre of mass, relative coordinates, and the reduced mass: infer an input with uncertainty

The reduced mass μ = m₁m₂/(m₁ + m₂) is the inertia of the separation r₁ − r₂ of two interacting particles: once the free centre-of-mass motion is split off, the pair's internal problem is exactly a one-body problem of mass μ in the potential V(r). Use the supplied topic model Y_out = 1/(1+10^(-q)), where Y_out is REDUCED MASS μ/mₑ (dimensionless). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793. q is Partner mass, log₁₀(m₂/mₑ), dimensionless. Keep no other adjustable input fixed. For this exercise use only 0.40375 ≤ q ≤ 3.39625 on this continuous branch. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. A reading gives Y_out = 0.99413497, with a bounded reading uncertainty ±0.00081954. Treat the model and all fixed inputs as exact for this exercise; the bound is not a standard deviation. First estimate the unknown q by straight-line interpolation between the two endpoint predictions. Then solve the actual model on the stated branch to an absolute input tolerance of 0.00029925, using a numerical bracket if required. Find the full input interval consistent with the bounded reading uncertainty and compare it with a symmetric input-error assumption. Do not assume that the supplied calibration points prove monotonicity outside this branch.

Explore the question data

REDUCED MASS μ/mₑ against q

Predictions from the supplied Centre of mass, relative coordinates, and the reduced mass model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law.

Vertical axis (y): REDUCED MASS μ/mₑ

REDUCED MASS μ/mₑ against qPredictions from the supplied Centre of mass, relative coordinates, and the reduced mass model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law. Horizontal axis: q: Partner mass, log₁₀(m₂/mₑ). Vertical axis: REDUCED MASS μ/mₑ. Exact values are available in the data table below.0.70570.7820.85830.93461.0110.28411.0921.92.7083.516xy

Horizontal axis (x): q: Partner mass, log₁₀(m₂/mₑ)

Axes show the supplied calibration interval; the origin may lie outside the plot.

Reading 1q: Partner mass, log₁₀(m₂/mₑ): 0.4037REDUCED MASS μ/mₑ: 0.717
Read the exact data as a table
REDUCED MASS μ/mₑ against q — supplied values
q: Partner mass, log₁₀(m₂/mₑ)REDUCED MASS μ/mₑ
0.403750.7170080734221427
1.1518750.9341520057683236
1.90.9875672647455576
2.6481250.9977566366257081
3.39624999999999980.9995986015973534

These are the supplied values, not a worked answer. No fitted trend is drawn.

Show a hint

The model's endpoint predictions bracket the reading. Solve Y_out(q) = Y_measured and then solve again at Y_measured − u and Y_measured + u; a nonlinear inverse can give unequal input deviations.

Reveal the worked solution
  1. Endpoint predictions are Y_out(0.40375) = 0.717008 and Y_out(3.39625) = 0.999599. The target lies between them. On the selected branch the response is strictly increasing.
  2. Endpoint interpolation gives q_line = 0.40375 + (0.994135 − 0.717008)(3.39625 − 0.40375)/(0.999599 − 0.717008) = 3.33839. This estimates the inverse of the endpoint chord, rather than assuming that chord is the physical model.
  3. Use the actual equation, not the chord, and bracket its root. Evaluating the midpoint and retaining the sign-changing half-interval gives q = 2.22918; substituting back gives Y_out = 0.99413497.
  4. The interpolation error in the input is |q_line − q| = 1.10922. This is larger than the requested numerical tolerance.
  5. Invert both limits Y_out = 0.99331543 and 0.99495451. Sort the roots even if the response decreases: 2.17201 ≤ q ≤ 2.2949.
  6. The lower and upper input deviations are 0.0571614 and 0.0657248. They differ because the inverse response is nonlinear; a symmetric error bar would only be a local approximation. This interval includes reading uncertainty only, not model error or uncertainty in fixed inputs.

Answer q ≈ 2.22918; compatible interval [2.17201, 2.2949]. Endpoint interpolation gives 3.33839.

Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.

Extra challenging · 03

The Heisenberg picture, conservation and Ehrenfest's theorem: infer an input with uncertainty

In the Heisenberg picture the state stays at |ψ(0)⟩ and each observable carries the time dependence, A_H(t) = U†(t)AU(t), evolving by dA_H/dt = (i/ħ)[H_H, A_H] + (∂A/∂t)_H, with every prediction the same as in the Schrödinger picture. Use the supplied topic model Y_out = -(x0+b*(x0^3+3*x0*s^2)), where Y_out is MEAN FORCE ⟨F⟩ = d⟨p⟩/dt (kℓ). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793. s is Packet width σ, measured in ℓ. Keep x0 (Packet centre ⟨x⟩) = 0.8 ℓ; b (Anharmonicity β = 4λℓ²/k) = 0.6 fixed. For this exercise use only 0.153125 ℓ ≤ s ≤ 0.546875 ℓ on this continuous branch. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. A reading gives Y_out = -1.3299604 kℓ, with a bounded reading uncertainty ±0.028349 kℓ. Treat the model and all fixed inputs as exact for this exercise; the bound is not a standard deviation. First estimate the unknown s by straight-line interpolation between the two endpoint predictions. Then solve the actual model on the stated branch to an absolute input tolerance of 0.000039375 ℓ, using a numerical bracket if required. Find the full input interval consistent with the bounded reading uncertainty and compare it with a symmetric input-error assumption. Do not assume that the supplied calibration points prove monotonicity outside this branch.

Explore the question data

MEAN FORCE ⟨F⟩ = d⟨p⟩/dt against s

Predictions from the supplied The Heisenberg picture, conservation and Ehrenfest's theorem model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law.

Vertical axis (y): MEAN FORCE ⟨F⟩ = d⟨p⟩/dt / kℓ

MEAN FORCE ⟨F⟩ = d⟨p⟩/dt against sPredictions from the supplied The Heisenberg picture, conservation and Ehrenfest's theorem model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law. Horizontal axis: s: Packet width σ / ℓ. Vertical axis: MEAN FORCE ⟨F⟩ = d⟨p⟩/dt / kℓ. Exact values are available in the data table below.-1.554-1.447-1.339-1.232-1.1250.13740.24370.350.45630.5626xy

Horizontal axis (x): s: Packet width σ / ℓ

Axes show the supplied calibration interval; the origin may lie outside the plot.

Reading 1s: Packet width σ / ℓ: 0.1531MEAN FORCE ⟨F⟩ = d⟨p⟩/dt / kℓ: -1.141
Read the exact data as a table
MEAN FORCE ⟨F⟩ = d⟨p⟩/dt against s — supplied values
s: Packet width σ / ℓMEAN FORCE ⟨F⟩ = d⟨p⟩/dt / kℓ
0.153125-1.1409640625000002
0.2515625-1.198328515625
0.35-1.2836
0.4484375-1.396778515625
0.546875-1.5378640625000002

These are the supplied values, not a worked answer. No fitted trend is drawn.

Show a hint

The model's endpoint predictions bracket the reading. Solve Y_out(s) = Y_measured and then solve again at Y_measured − u and Y_measured + u; a nonlinear inverse can give unequal input deviations.

Reveal the worked solution
  1. Endpoint predictions are Y_out(0.153125) = -1.14096 kℓ and Y_out(0.546875) = -1.53786 kℓ. The target lies between them. On the selected branch the response is strictly decreasing.
  2. Endpoint interpolation gives s_line = 0.153125 + (-1.32996 − -1.14096)(0.546875 − 0.153125)/(-1.53786 − -1.14096) = 0.340621 ℓ. This estimates the inverse of the endpoint chord, rather than assuming that chord is the physical model.
  3. Use the actual equation, not the chord, and bracket its root. Evaluating the midpoint and retaining the sign-changing half-interval gives s = 0.393312 ℓ; substituting back gives Y_out = -1.3299604 kℓ.
  4. The interpolation error in the input is |s_line − s| = 0.0526911 ℓ. This is larger than the requested numerical tolerance.
  5. Invert both limits Y_out = -1.3583094 kℓ and -1.3016114 kℓ. Sort the roots even if the response decreases: 0.367434 ℓ ≤ s ≤ 0.41759 ℓ.
  6. The lower and upper input deviations are 0.0258783 ℓ and 0.0242776 ℓ. They differ because the inverse response is nonlinear; a symmetric error bar would only be a local approximation. This interval includes reading uncertainty only, not model error or uncertainty in fixed inputs.

Answer s ≈ 0.393312 ℓ; compatible interval [0.367434, 0.41759] ℓ. Endpoint interpolation gives 0.340621 ℓ.

Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.

Extra challenging · 04

Tensor-product spaces for two subsystems: infer an input with uncertainty

The tensor product H_A ⊗ H_B is the state space of systems A and B taken together: it is spanned by the product kets |i⟩|j⟩ of basis kets of each part, so it has d_A d_B dimensions, and any superposition Σ cᵢⱼ|i⟩|j⟩ of them is a state. Use the supplied topic model Y_out = (200*(cosd(th1/2)*cosd(th2/2)*sind(th1/2)*sind(th2/2)+cosd(th1/2)*sind(th2/2)*sind(th1/2)*cosd(th2/2)))/100, where Y_out is ⟨σₓ ⊗ σₓ⟩ FROM THE COLUMN (before display rounding) (dimensionless). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793; sind/cosd/tand use degrees. th1 is Spin 1 polar angle θ₁, measured in °. Keep th2 (Spin 2 polar angle θ₂) = 150 ° fixed. For this exercise use only 283.95 ° ≤ th1 ≤ 321.75 ° on this continuous branch. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. A reading gives Y_out = -0.39927574, with a bounded reading uncertainty ±0.012897. Treat the model and all fixed inputs as exact for this exercise; the bound is not a standard deviation. First estimate the unknown th1 by straight-line interpolation between the two endpoint predictions. Then solve the actual model on the stated branch to an absolute input tolerance of 0.00378 °, using a numerical bracket if required. Find the full input interval consistent with the bounded reading uncertainty and compare it with a symmetric input-error assumption. Do not assume that the supplied calibration points prove monotonicity outside this branch.

Explore the question data

⟨σₓ ⊗ σₓ⟩ FROM THE COLUMN (before display rounding) against th1

Predictions from the supplied Tensor-product spaces for two subsystems model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law.

Vertical axis (y): ⟨σₓ ⊗ σₓ⟩ FROM THE COLUMN (before display rounding)

⟨σₓ ⊗ σₓ⟩ FROM THE COLUMN (before display rounding) against th1Predictions from the supplied Tensor-product spaces for two subsystems model, with all other inputs fixed as stated in the question. 5 calibration points support a trend comparison; they are not measured data or a straight-line law. Horizontal axis: th1: Spin 1 polar angle θ₁ / °. Vertical axis: ⟨σₓ ⊗ σₓ⟩ FROM THE COLUMN (before display rounding). Exact values are available in the data table below.-0.4923-0.4448-0.3974-0.35-0.3025282.4292.6302.9313.1323.3xy

Horizontal axis (x): th1: Spin 1 polar angle θ₁ / °

Axes show the supplied calibration interval; the origin may lie outside the plot.

Reading 1th1: Spin 1 polar angle θ₁ / °: 283.9⟨σₓ ⊗ σₓ⟩ FROM THE COLUMN (before display rounding): -0.4853
Read the exact data as a table
⟨σₓ ⊗ σₓ⟩ FROM THE COLUMN (before display rounding) against th1 — supplied values
th1: Spin 1 polar angle θ₁ / °⟨σₓ ⊗ σₓ⟩ FROM THE COLUMN (before display rounding)
283.95-0.4852532367342713
293.4-0.4588773128419906
302.85-0.4200467769494708
312.3-0.36981554748930484
321.75-0.30954697465491715

These are the supplied values, not a worked answer. No fitted trend is drawn.

Show a hint

The model's endpoint predictions bracket the reading. Solve Y_out(th1) = Y_measured and then solve again at Y_measured − u and Y_measured + u; a nonlinear inverse can give unequal input deviations.

Reveal the worked solution
  1. Endpoint predictions are Y_out(283.95) = -0.485253 and Y_out(321.75) = -0.309547. The target lies between them. On the selected branch the response is strictly increasing.
  2. Endpoint interpolation gives th1_line = 283.95 + (-0.399276 − -0.485253)(321.75 − 283.95)/(-0.309547 − -0.485253) = 302.446 °. This estimates the inverse of the endpoint chord, rather than assuming that chord is the physical model.
  3. Use the actual equation, not the chord, and bracket its root. Evaluating the midpoint and retaining the sign-changing half-interval gives th1 = 307.008 °; substituting back gives Y_out = -0.39927574.
  4. The interpolation error in the input is |th1_line − th1| = 4.56151 °. This is larger than the requested numerical tolerance.
  5. Invert both limits Y_out = -0.41217274 and -0.38637874. Sort the roots even if the response decreases: 304.478 ° ≤ th1 ≤ 309.398 °.
  6. The lower and upper input deviations are 2.53019 ° and 2.38984 °. They differ because the inverse response is nonlinear; a symmetric error bar would only be a local approximation. This interval includes reading uncertainty only, not model error or uncertainty in fixed inputs.

Answer th1 ≈ 307.008 °; compatible interval [304.478, 309.398] °. Endpoint interpolation gives 302.446 °.

Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.

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