University Quantum Mechanics II · topic UQMII-08.04
Evaluating spin-orbit coupling in the coupled basis
Connect the ideas, make your working visible, and test the result. Use the hints when you need a starting point; open the full solution after your attempt.
Further practice
Work through a fresh case before tackling the extension.
Evaluating spin-orbit coupling in the coupled basis: predict a finite change
The first-order spin-orbit shift of a hydrogen level is the expectation value of Hₛₒ in a coupled state |n, l, ½, j, mⱼ⟩: the eigenvalue of S⋅L, fixed by j and l, times the radial average of e²/(8πε₀m²c²r³). Use the supplied topic model Y_out = -350.377*min(l,1)/(4*(nr+l+1)^3*max(l,1)*(l+0.5)), where Y_out is SHIFT OF j = l − ½ (GHz). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793; min(a,b) selects the smaller value; max(a,b) selects the larger value. l is Orbital quantum number l, dimensionless. Keep nr (Radial nodes nᵣ = n − l − 1) = 0 fixed. For this exercise use only 1 ≤ l ≤ 4, at the specified test settings separated by 1. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. Calculate Y_out at l = 2 and 3. Find the signed output change ΔY_out and the average sensitivity ΔY_out/Δl across this interval. State whether the response increases or decreases; explain why a finite difference between these settings does not require interpolation between them.
SHIFT OF j = l − ½ against l
Predictions from the supplied Evaluating spin-orbit coupling in the coupled basis model, with all other inputs fixed as stated in the question. 4 calibration points support a trend comparison; they are not measured data or a straight-line law.
Vertical axis (y): SHIFT OF j = l − ½ / GHz
Horizontal axis (x): l: Orbital quantum number l
Axes show the supplied calibration interval; the origin may lie outside the plot.
Read the exact data as a table
| l: Orbital quantum number l | SHIFT OF j = l − ½ / GHz |
|---|---|
| 1 | -7.299520833333333 |
| 2 | -0.6488462962962963 |
| 3 | -0.1303485863095238 |
| 4 | -0.03893077777777778 |
These are the supplied values, not a worked answer. No fitted trend is drawn.
Show a hint
Substitute each value of l separately while keeping every other input fixed, then subtract in the same order.
Reveal the worked solution
- At l = 2, substitute into Y_out = -350.377*min(l,1)/(4*(nr+l+1)^3*max(l,1)*(l+0.5)): Y₀ = -0.648846 GHz.
- At l = 3, the same fixed-parameter model gives Y₁ = -0.130349 GHz.
- Signed change: ΔY_out = Y₁ − Y₀ = 0.518498 GHz; the input change is Δl = 1.
- Average sensitivity is ΔY_out/Δl = 0.518498 GHz per unit input. Its positive sign means that this response increases over the specified interval.
- This finite difference compares two specified test settings without interpolating between them. A point derivative is not required. Any quantum numbers or particle counts must also obey their physical admissibility conditions.
Answer Y₀ = -0.648846 GHz, Y₁ = -0.130349 GHz; ΔY_out = 0.518498 GHz; average sensitivity = 0.518498 GHz per unit input.
Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.
Extra challenging questions
Work through the linked stages and explain what each result means.
Evaluating spin-orbit coupling in the coupled basis: infer an input with uncertainty
The first-order spin-orbit shift of a hydrogen level is the expectation value of Hₛₒ in a coupled state |n, l, ½, j, mⱼ⟩: the eigenvalue of S⋅L, fixed by j and l, times the radial average of e²/(8πε₀m²c²r³). Use the supplied topic model Y_out = -350.377*min(l,1)/(4*(nr+l+1)^3*max(l,1)*(l+0.5)), where Y_out is SHIFT OF j = l − ½ (GHz). The output symbol Y_out is distinct from all input symbols. ^ denotes a power; π = 3.141592653589793; min(a,b) selects the smaller value; max(a,b) selects the larger value. l is Orbital quantum number l, dimensionless. Keep nr (Radial nodes nᵣ = n − l − 1) = 0 fixed. For this exercise use only 1 ≤ l ≤ 4, at the specified test settings separated by 1. A grid of test settings is an input restriction for this exercise, not by itself a claim of physical quantisation. This calculation retains the topic model's stated assumptions; it does not extend them to a different physical setup. A reading gives Y_out = -0.13034859 GHz, with a bounded reading uncertainty ±0.58085 GHz. Treat the model and all fixed inputs as exact for this exercise; the bound is not a standard deviation. Determine every allowed value of l consistent with that bound. Compare with a straight-line interpolation between the two endpoint predictions, and explain why a fractional setting may be inadmissible. Do not assume that the supplied calibration points prove monotonicity outside this branch.
SHIFT OF j = l − ½ against l
Predictions from the supplied Evaluating spin-orbit coupling in the coupled basis model, with all other inputs fixed as stated in the question. 4 calibration points support a trend comparison; they are not measured data or a straight-line law.
Vertical axis (y): SHIFT OF j = l − ½ / GHz
Horizontal axis (x): l: Orbital quantum number l
Axes show the supplied calibration interval; the origin may lie outside the plot.
Read the exact data as a table
| l: Orbital quantum number l | SHIFT OF j = l − ½ / GHz |
|---|---|
| 1 | -7.299520833333333 |
| 2 | -0.6488462962962963 |
| 3 | -0.1303485863095238 |
| 4 | -0.03893077777777778 |
These are the supplied values, not a worked answer. No fitted trend is drawn.
Show a hint
Enumerate the permitted settings in the stated range, evaluate Y_out at each, and retain every setting satisfying |Y_out − Y_measured| ≤ u. The plotted predictions are supplied calibration evidence.
Reveal the worked solution
- Endpoint predictions are Y_out(1) = -7.29952 GHz and Y_out(4) = -0.0389308 GHz. The target lies between them. On the selected branch the response is strictly increasing.
- Endpoint interpolation gives l_line = 1 + (-0.130349 − -7.29952)(4 − 1)/(-0.0389308 − -7.29952) = 3.96223. This estimates the inverse of the endpoint chord, rather than assuming that chord is the physical model.
- Evaluate the model at each permitted setting. The central reading corresponds to l = 3; only the allowed settings 2, 3, 4 lie inside the stated reading bound.
- The interpolation error in the input is |l_line − l| = 0.962227.
- The compatible allowed values span 2 to 4. Values between specified test settings are outside this exercise's input domain even if an interpolation passes through them.
- The quoted output bound restricts which specified settings remain compatible. It does not change physical restrictions on quantum numbers or counts, and the chosen grid alone does not establish physical quantisation.
Answer Compatible l: 2, 3, 4. Endpoint interpolation predicts 3.96223; check admissibility against the discrete settings.
Compare the assumptions, method and units with your attempt. Explain any correction before trying another question.