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Quantum core · institution-dependent · Interactive lesson

Free evolution, group velocity and spreading

A single plane wave is everywhere at once and describes no particle. Add a band of them and you get something localised that moves — but the free-particle dispersion is quadratic, so the components run at different speeds. This lesson settles which speed is the particle's, and how long being localised lasts.

UPIV-05.07 · Lesson 7 of 9 in this unit. Position is not a completion score.
Starting model: Free evolution, group velocity and spreadingThe real part of a free electron packet inside its dashed Gaussian envelope, plotted against position over 0 to 40 nm. The filled dot rides the envelope centre at v_g; the open dot is the crest that left with it at 5 nm, now 2.78 nm behind because v_p = v_g/2. The rms width has grown from 2.00 to 2.12 nm. Carrier drawn at the central k.Re ψ(x, t): free electron packet, V = 0xc = 10.6 nm · crest = 7.8 nm · lag = 2.78 nm040 nm● envelope centre, moving at vg○ carrier crest, moving at vₚ = vg/2
Start with a picture. Change the model in the lab below.

Quantum core · institution-dependent. Departments differ in how much quantum mechanics they include in Physics IV or teach in a dedicated course. Follow your university’s required mathematical depth and assessment; these numbered units are not automatically optional.

1

Build the model

The envelope goes at one speed, the crests inside it at another.

The key idea

A free wave packet is a superposition of plane waves in which time only multiplies each component by e(−iħk²t/2m): the envelope travels at the group velocity ħk₀/m while its width grows from the spread of speeds it already contained.

Example. An electron localised to σ₀ = 1.0 nm already carries σₚ = ħ/2σ₀ = 5.3 × 10⁻²⁶ kg m s⁻¹, a velocity spread of 58 km s⁻¹, so it is 1.4 nm wide after τ = 17 fs and about 58 μm wide one nanosecond later.

The complete physical model and assumptions

Localisation has to be bought with a band of wavenumbers. Superpose that band — Ψ(x, t) = (2π)(−1/2) ∫ φ(k) e(i[kx − ω(k)t]) dk — and free evolution becomes trivial in k-space, because each component keeps its amplitude and only collects the phase e(−iħk²t/2m). Everything then follows from the one dispersion relation ω = ħk²/2m. Expand it about the central k₀: the first derivative, dω/dk = ħk₀/m, is the speed at which the whole envelope translates, and it equals p₀/m, the classical velocity — while ω/k₀ = ħk₀/2m, exactly half of it, belongs to the crests inside the envelope and moves no probability anywhere. The second derivative, d²ω/dk² = ħ/m, refuses to vanish, and that is the price of the model: the components dephase, and for a Gaussian the width obeys σₓ(t) = σ₀√(1 + (t/τ)²) with τ = 2mσ₀²/ħ. Nothing is pushing the packet open. The momentum distribution is frozen, because p̂ commutes with the free Hamiltonian; what you are watching is a fixed spread of speeds σₚ/m flying apart from a common start. Localisation is therefore a loan, and the more tightly you take it out the sooner it is called in — τ goes as σ₀², so an electron pinned to a nanometre is 41% wider after just 17 femtoseconds.

1Free evolution is trivial once you work in k

Take whatever state you prepared at t = 0 and resolve it into plane waves: φ(k) = (2π)(−1/2) ∫ Ψ(x,0) e(−ikx) dx. Each plane wave is an exact solution of the free time-dependent Schrödinger equation provided it turns at its own rate ω(k) = ħk²/2m, so the state at later times is Ψ(x, t) = (2π)(−1/2) ∫ φ(k) e(i[kx − ω(k)t]) dk. Notice what that does and does not change. Every |φ(k)| is untouched — free evolution multiplies each component by a pure phase — so the momentum probability density, and with it ⟨p⟩ and σₚ, is frozen for all time. All the drama happens in position space, and it is interference: the components start in step at t = 0 and drift out of step at rates set by their own ω. The working method follows. Transform to k, attach one phase per component, transform back.

2One derivative moves the packet, the next one spreads it

Suppose φ(k) is concentrated near some k₀. Write ω(k) = ω₀ + (dω/dk)₀(k − k₀) + ½(d²ω/dk²)₀(k − k₀)² and put it back into the integral. The constant term is an overall phase and does nothing observable. The linear term factors into e(i(k−k₀)(x − vg t)), which says the envelope has simply been translated bodily by vg t, with vg = (dω/dk)₀ = ħk₀/m = p₀/m — exactly the classical speed. Truncate there and the packet is rigid forever. The quadratic term is what spoils that: for a free particle d²ω/dk² = ħ/m, which is never zero, so each component's phase runs ahead or behind by an amount growing as t(k − k₀)², and the superposition unravels. Compare light in vacuum, where ω = ck makes the second derivative vanish and a pulse keeps its shape indefinitely. A 150 eV electron has k₀ = 6.28 × 10¹⁰ m⁻¹ and vg = 7.27 × 10⁶ m s⁻¹; the same expansion that gives that speed also guarantees the spreading.

3The phase velocity is half the particle's, and carries nothing

The crests inside the envelope move at vₚ = ω/k = E/p. Non-relativistically E = p²/2m, so vₚ = p/2m = vg/2: the crests fall steadily backwards through the packet, losing one wavelength for every two the envelope advances. Two arguments show vₚ cannot be a physical speed. First, it depends on where you put the zero of energy — add a constant V₀ everywhere and every ω shifts by V₀/ħ, so vₚ changes while not one measurable prediction does, whereas dω/dk is untouched. Second, if you keep the rest energy and write E = √((pc)² + (mc²)²), then vₚ = E/p = c²/v, which exceeds c for every massive particle. Nothing is wrong, because a single crest carries no probability anywhere: a pure plane wave has the same |Ψ|² at every point and no feature you could time. What does move is the envelope, and Ehrenfest's theorem confirms it — for V = 0, d⟨x⟩/dt = ⟨p⟩/m and d⟨p⟩/dt = 0, exactly, so the centroid drifts at the classical speed forever.

4The Gaussian width law and its single timescale

Take the minimum-uncertainty Gaussian, |Ψ(x,0)|² ∝ e(−x²/2σ₀²). Its transform is Gaussian too, with σₖ = 1/(2σ₀). Attaching e(−iħk²t/2m) to each component and completing the square turns the real width σ₀² into the complex σ₀²(1 + it/τ), and reading off the modulus gives σₓ(t) = σ₀√(1 + (t/τ)²) with τ = 2mσ₀²/ħ. One number runs the whole story. Below τ the width hardly moves, since σₓ ≈ σ₀(1 + t²/2τ²); above it the root goes linear and σₓ → σ₀t/τ. The peak of |Ψ| falls as σₓ(−1/2), which is exactly what holds the norm at one. Now feel the σ₀² scaling. An electron localised to 1.0 nm has τ = 2 × 9.11 × 10⁻³¹ × 10⁻¹⁸ ÷ 1.055 × 10⁻³⁴ = 17 fs, and one nanosecond later it is 58 μm across. A 1 g bead localised to 1 mm has τ ≈ 1.9 × 10²⁵ s, some 4 × 10⁷ times the age of the universe. Tighter preparation is not safer; it is the very thing that makes spreading fast.

5Nothing pushes it apart — a frozen velocity spread flies free

It is tempting to read spreading as a force, or as the particle dissolving. It is neither. Because p̂ commutes with the free Hamiltonian, σₚ is a constant of the motion — exactly constant, not approximately — so the packet is carrying the same spread of speeds σᵥ = σₚ/m that it had at t = 0, and at late times its width simply grows as σₓ → σᵥ t. A classical cloud of particles released from one point with a spread of velocities does precisely the same thing, and nobody calls that a force. What is quantum about it is the floor underneath: you cannot make σᵥ small while σₓ(0) is also small, because σₓσₚ ≥ ħ/2. One consequence is worth carrying forward. The minimum-uncertainty Gaussian does not stay minimum-uncertainty: with σₚ pinned and σₓ growing, σₓσₚ = (ħ/2)√(1 + (t/τ)²), so the state leaves the floor the instant it starts evolving and never comes back to it.

6Spreading is an asymptotic statement, not an instantaneous one

For any free packet x̂(t) = x̂(0) + p̂t/m, and squaring the deviation gives σₓ²(t) = σₓ²(0) + (C₀/m)t + (σₚ/m)²t², where C₀ = ⟨Δx̂Δp̂ + Δp̂Δx̂⟩₀ is the symmetrised position–momentum correlation at t = 0. That is an upward parabola in t, and what happens at the very first instant is set entirely by the sign of C₀. The minimum-uncertainty Gaussian has C₀ = 0 and starts widening immediately. A packet prepared converging has C₀ < 0: it narrows until t* = −mC₀/2σₚ², bottoming out at σₘᵢₙ² = σₓ²(0) − C₀²/4σₚ², and only then spreads. That is not a curiosity — it is what an electron lens does, imposing exactly such a correlation so the beam comes to a focus downstream. What no preparation escapes is the t² term, which eventually dominates whatever C₀ you chose. Spreading is unconditional in the limit, never at every instant.

2

Key equations

Read the units, assumptions and limits before substituting.

Free packet and its one time factor

Ψ(x, t) = (2π)(−1/2) ∫ φ(k) e(i[kx − ω(k)t]) dk

Free evolution touches only the phase of each component, so the momentum distribution never changes.

φ(k) is fixed once by Ψ(x,0); k in m⁻¹, ω in rad s⁻¹, and |φ(k)|² is the wavenumber probability density

Free-particle dispersion relation

ω(k) = ħk²/2m

Quadratic, not linear — which is the whole reason a matter packet spreads and a light pulse in vacuum does not.

from E = ħω and E = p²/2m with p = ħk; ħ/m = 1.16 × 10⁻⁴ m² s⁻¹ for an electron

Group velocity and phase velocity

vg = dω/dk = ħk₀/m = p₀/mvₚ = ω₀/k₀ = ħk₀/2m = vg/2

vg is the classical particle speed; vₚ shifts when you move the zero of energy, so it can carry nothing.

both in m s⁻¹; vg belongs to the envelope, vₚ to the crests inside it

Gaussian width law

σₓ(t) = σ₀ √(1 + (t/τ)²), τ = 2mσ₀²/ħ

Below τ the width barely moves; above it σₓ grows linearly. Halving σ₀ quarters τ.

σ₀ the initial rms width in m, τ the spreading time in s; τ ∝ σ₀², so tighter means faster

The momentum spread is frozen

σₚ(t) = σₚ(0), and σₚ = ħ/2σ₀ at minimum uncertainty

Late-time spreading is free flight of a fixed velocity spread: σₓ → (σₚ/m) t.

[p̂, Ĥ] = 0 when V = 0, so |φ(k)|² cannot move; σₚ in kg m s⁻¹

Width of any free packet

σₓ²(t) = σₓ²(0) + (C₀/m) t + (σₚ/m)² t²

A parabola in t whose vertex sits at t* = −mC₀/2σₚ², so a converging packet narrows first and only then spreads.

C₀ = ⟨Δx̂Δp̂ + Δp̂Δx̂⟩₀ in J s; C₀ < 0 is a converging packet, C₀ = 0 a Gaussian at its narrowest
3

Interactive lab

Predict first. Explore the model. Compare the result.

Explore the model

24 fs
0 to 60 fs; steps of 1.
2.0 nm
1 to 3 nm; steps of 0.1.
2.0 nm⁻¹
1.2 to 2.6 nm⁻¹; steps of 0.1.

Try this. Drag t and watch the open crest slip back through the packet — one wavelength lost for every two the envelope gains, since vₚ = vg/2. Then cut σ₀ from 3 nm to 1.5 nm: the packet starts taller and narrower but spreads four times sooner, because τ goes as σ₀².

Live results

GROUP SPEED vg
0.232 nm/fs
PHASE SPEED vₚ
0.116 nm/fs
SPREADING TIME τ
69.1 fs
RMS WIDTH σ(t)
2.12 nm

Results follow this lesson’s model and assumptions. Displayed values are rounded.

Interactive Physics IV modelThe real part of a free electron packet inside its dashed Gaussian envelope, plotted against position over 0 to 40 nm. The filled dot rides the envelope centre at v_g; the open dot is the crest that left with it at 5 nm, now 2.78 nm behind because v_p = v_g/2. The rms width has grown from 2.00 to 2.12 nm. Carrier drawn at the central k.Re ψ(x, t): free electron packet, V = 0xc = 10.6 nm · crest = 7.8 nm · lag = 2.78 nm040 nm● envelope centre, moving at vg○ carrier crest, moving at vₚ = vg/2
The real part of a free electron packet inside its dashed Gaussian envelope, plotted against position over 0 to 40 nm. The filled dot rides the envelope centre at vg; the open dot is the crest that left with it at 5 nm, now 2.78 nm behind because vₚ = vg/2. The rms width has grown from 2.00 to 2.12 nm. Carrier drawn at the central k.

Predict → change one variable → check

Plan a change before running it. Every other input stays at the saved baseline.

Saved baseline. Elapsed time t: 24 fs; Initial rms width σ₀: 2.0 nm; Central wavenumber k₀: 2.0 nm⁻¹

Baseline 24; choose 0 to 60, in steps of 1.
4. Compared with the saved baseline, this result will…

This experiment is kept only while this page is open. It does not change saved course progress.

4

Catch the common trap

The error is reading "a free packet spreads" as "a free packet is always spreading". The width obeys σₓ²(t) = σₓ²(0) + (C₀/m)t + (σₚ/m)²t², a parabola in t whose linear coefficient is the initial position–momentum correlation C₀ = ⟨Δx̂Δp̂ + Δp̂Δx̂⟩₀. Only when C₀ = 0 — the minimum-uncertainty Gaussian caught at its narrowest — does growth begin at once. Prepare the packet with C₀ < 0 and the first thing it does is get smaller, right up to t* = −mC₀/2σₚ². What is unconditional is the late-time law σₓ → (σₚ/m)t, because the t² term always wins in the end. A quieter version of the same mistake is imagining something inside the packet pushing it open. Nothing is: the momentum distribution never changes, and the widening is a fixed spread of speeds separating.

5

Practice & worked examples

3 authored examples. Make an attempt, then reveal the reasoning one step at a time.

EasyExample 1

A free electron packet is centred on the de Broglie wavelength λ₀ = 0.100 nm. Find the central wavenumber, the group velocity, the phase velocity, and the packet's central kinetic energy in eV. Take mₑ = 9.109 × 10⁻³¹ kg and ħ = 1.0546 × 10⁻³⁴ J s.

Sketch your answer or reasoning, then compare it with the authored solution. Your writing is not automatically graded or saved.

0 of 4 steps revealed.

MediumExample 2

An electron is prepared in a minimum-uncertainty Gaussian of rms width σ₀ = 2.0 nm. Find σₚ, the velocity spread σₚ/m, the spreading time τ = 2mσ₀²/ħ, the rms width at t = 50 fs, and the uncertainty product at that moment in units of ħ.

Sketch your answer or reasoning, then compare it with the authored solution. Your writing is not automatically graded or saved.

0 of 5 steps revealed.

HardExample 3

A free electron packet has σₓ = 5.0 nm and σₚ = 3.0 × 10⁻²⁶ kg m s⁻¹ at t = 0, with a symmetrised correlation C₀ = ⟨Δx̂Δp̂ + Δp̂Δx̂⟩₀ = −2.0 × 10⁻³⁴ J s. Find when the packet is narrowest and how narrow, when it returns to 5.0 nm, and its width at t = 1.0 ps.

Sketch your answer or reasoning, then compare it with the authored solution. Your writing is not automatically graded or saved.

0 of 6 steps revealed.

6

Quick check

Select an answer and explain it before checking.

A free electron is prepared as a minimum-uncertainty Gaussian of rms width σ₀ = 1.0 nm, so its spreading time is τ = 2mσ₀²/ħ = 17 fs. Which statement correctly describes the packet at t = 17 fs?
7

Review & continue

A free wave packet is a superposition of plane waves in which time only multiplies each component by e(−iħk²t/2m): the envelope travels at the group velocity ħk₀/m while its width grows from the spread of speeds it already contained.

  • Explain the relationship without looking at the equation.
  • Check a sign, a unit and a model assumption in your working.
  • Return to the lab or worked example if a step is still unclear.

Extra challenging questions

Connect several ideas, explore supplied data, and compare your reasoning with a worked solution.